Synthesis, Characterization and Investigation of Electrochemical and Spectroelectrochemical Properties of Peripherally Tetra Diethoxypropan Substituted Phthalocyanines


Akyuz D., AKÇAY H. T., BAYRAK R.

ELECTROANALYSIS, cilt.33, sa.1, ss.146-151, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 33 Sayı: 1
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1002/elan.202060250
  • Dergi Adı: ELECTROANALYSIS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, BIOSIS, Chemical Abstracts Core, Chimica, Communication Abstracts, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.146-151
  • Anahtar Kelimeler: phthalocyanine, 1, 3-diethoxy-2-propanol, electrochemistry, spectroelectrochemistry, electrocolorimetry, METAL-FREE, ABSORPTION, ZINC(II), COPPER(II), COBALT
  • Recep Tayyip Erdoğan Üniversitesi Adresli: Evet

Özet

In this study novel peripherally tetra 1,3-diethoxy-2-propanol substituted Co(II), Cu(II), Mg(II), Ni(II) Zn(II) phthalocyanine derivatives were prepared. The characterization of the novel compounds was made by FT-IR,H-1-NMR, UV-vis and MALDI-TOF mass. Electrochemical,in-situspectroelectrochemical and electrocolorimetric measurements have been carried out with the aim to determine the redox properties, to illuminate reaction mechanism and the effect of substituent and metal center. Moreover, the color properties and aggregation tendency of compounds were also investigated.