Enhanced photocatalytic hydrogen evolution via SiC loaded CeO2 nanofiber composite


Genc M. T., Sarilmaz A., Aslan E., ÖZEL F., Patir I. H.

Inorganic Chemistry Communications, cilt.175, 2025 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 175
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1016/j.inoche.2025.114203
  • Dergi Adı: Inorganic Chemistry Communications
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica, DIALNET
  • Anahtar Kelimeler: Dye sensitized, Hydrogen evolution, Lanthanide group transition metal oxide
  • Recep Tayyip Erdoğan Üniversitesi Adresli: Evet

Özet

CeO2 is a significant material in the photocatalytic hydrogen evolution reactions due to the high creating ability of oxygen vacancies, high chemical stability and excellent redox properties. However, the wide band gap of CeO2 limits the visible light absorption. In this study, SiC loaded to CeO2 nanofiber catalyst by electrospinning methods to improve the light absorption efficiency and increase the active surface area result in enhanced photocatalytic performance. In the photocatalytic hydrogen evolution reactions medium, which contain eosin Y dye and triethanolamine as a photosensitizer and an electron donor, respectively. The addition of SiC to CeO2 improve the visible light absorption rate, electron transfer efficiency. The hydrogen production rate of CeO2/SiC nanofiber catalyst reaches to 5208 μmol g−1 under visible light irradiation, it is approximately 13- and 2-times higher than SiC and CeO2 nanofiber, respectively. Furthermore, CeO2/SiC nanofiber catalyst maintain more than half of it is photocatalytic activity after 3 cycles of reactions. Therefore, the CeO2/SiC nanofiber catalyst will provide innovative approaches to achieve efficient photocatalytic water splitting in the future, enabling the development of catalytic studies.