Non-peripherally tetra substituted phthalocyanines bearing benzodioxane moieties: Synthesis, characterization and investigation of electrochemical and spectroelectrochemical properties


DEMİRBAŞ Ü., Akyuz D., Akcay H. T. , KOCA A., KANTEKİN H.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1189, ss.234-239, 2019 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 1189
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1016/j.molstruc.2019.04.031
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Sayfa Sayıları: ss.234-239

Özet

The 1,4-benzodioxane substituted phthalonitrile compound (3) and non-peripherally tetra substituted cobalt(II) (4), nickel(II) (5) and copper(II) (6) phthalocyanine complexes were synthesized. The structural characterization of the compounds was performed by using various spectroscopic techniques. The electron transfer properties of the phthalocyanine complexes (4-6) were investigated by voltammetric and in situ spectroelectrochemical measurements. The electrochemical and spectroelectrochemical properties of the non-peripherally tetra substituted metallo-phthalocyanines (4-6) having redox active and inactive metal center were compared with each other in terms of electrochemical responses and the differences were revealed. (C) 2019 Elsevier B.V. All rights reserved.