Guaiacol Substituted AzaPCs: A Novel Synthesis Method and Investigation of Photophysical Properties


Kantar G. , Kaya M. , Sahin O., Sasmaz S.

JOURNAL OF STRUCTURAL CHEMISTRY, vol.59, no.3, pp.571-583, 2018 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 59 Issue: 3
  • Publication Date: 2018
  • Doi Number: 10.1134/s0022476618030101
  • Title of Journal : JOURNAL OF STRUCTURAL CHEMISTRY
  • Page Numbers: pp.571-583

Abstract

AzaPCs containing tetra- and octaguaiacol moieties have not been investigated up to now. In this study, an unusual method is used for the synthesis of metalloAzaPCs (M: Zn, Co, Cu) containing guaiacol moieties. All compounds are characterized by a combination of FT-IR, H-1 NMR, C-13 NMR, mass and UV/vis spectroscopy techniques. The molecular structure of starting pyrazine compounds 1 and 2 is also determined by the single crystal X-ray diffraction technique. The aggregation behavior of new Zn(II) AzaPCs is investigated in DMSO at different concentrations. The fluorescence properties of Zn(II) AzaPCs are investigated in different solvents. The fluorescence quantum yields of Zn(II) AzaPCs are calculated in DMSO.