DETERMINATION OF PROTONATION CONSTANTS OF SOME 3-ALKYL(ARYL)-4-(p-t-BUTYL(BENZYL/BENZYLIDEN)AMINO)-4,5-DIHYDRO-1H-1,2,4-TRIAZOLE-5-ONE DERIVATIVES IN ETHANOL-WATER MIXTURES


İSLAMOĞLU F. , AKSU İ. , Kahveci B., BEKİRCAN O.

BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, vol.24, no.2, pp.185-192, 2010 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 24 Issue: 2
  • Publication Date: 2010
  • Title of Journal : BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA
  • Page Numbers: pp.185-192

Abstract

Stoichiometric protonation constants of some 3-alkyl(aryl)-4-(p-t-butyl(benzyl/benzyliden)amino)-4,5-dihydro-1H-1,2,4-triazole-5-one derivatives were determined potentiometrically in 50% (v/v) ethanol-water mixtures at 25 degrees C with an ionic strength of 0.10 M. The calculation of the stoichiometric protonation constants was carried out using a PKAS computer program. The effect of solvents composition on the stoichiometric protonation constants are discussed.