A tetranuclear copper (II) complex with pyrazole-3,5-dicarboxylate ligands: synthesis, characterization and electrochemical properties

Demir S., CEPNI H. M., HOLYNSKA M., KAVANOZ M.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, cilt.71, sa.4, ss.305-310, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 71 Sayı: 4
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1515/znb-2015-0197
  • Dergi Adı: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.305-310
  • Anahtar Kelimeler: copper, crystal structure, polynuclear, pyrazole-3,5-dicarboxylic acid, thermal analysis, MAGNETIC-PROPERTIES, 3,5-PYRAZOLEDICARBOXYLIC ACID, CRYSTAL-STRUCTURES, CU(II) COMPLEXES, CHEMISTRY
  • Recep Tayyip Erdoğan Üniversitesi Adresli: Evet

Özet

A tetranuclear copper (II) complex with pyrazole3,5-dicarboxylate ligands (pdc(3-)), [Me2NH2](4) [Cu-4(pdc)(4)], was synthesized using solvothermal and metal oxidation routes and characterized by elemental analysis, infrared, thermogravimetry/differential thermal analysis, and room-temperature magnetic measurements. The structure of the complex was determined by single-crystal X-ray diffraction. It comprises dimethylammonium cations and complex anions containing four Cu2+ cations. The crystal structure is stabilized by N-H center dot center dot center dot O hydrogen bonds. In addition, the electrochemical behavior was studied.