Preparation and characterization of a novel activated carbon component via chemical activation of tea woody stem


Tabak A., SEVİMLİ K., Kaya M. , Caglar B.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, cilt.138, sa.6, ss.3885-3895, 2019 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 138 Konu: 6
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1007/s10973-019-08387-2
  • Dergi Adı: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Sayfa Sayıları: ss.3885-3895

Özet

The novel activated carbon materials were synthesized by the carbonization and chemical activation of agricultural bio-waste from tea woody stems (TWS), and these materials were characterized by using FTIR, SEM, TG/DTA and surface analysis (BET surface area; pore distribution; pore size, area and volume) techniques. The higher carbonization times and amount of chemical reagent generally produce the higher surface area at 400 and 500 degrees C. The experimental data demonstrated that the highest BET surface area was 789 m(2) g(-1) at 500 degrees C, 75 mu m particle size, TWS/KOH ratio of 1:2 and carbonization time of 3 h. The activated carbon IR spectrum showed the increases in intense of aromatic C-H out-of-plane bending and C=C vibrations and the disappearance of olefinic C=C functional groups. Thermal analysis curves of TWS are ascribed to decomposition of organic derivate corresponding to lignin, cellulose and hemicelluloses components up to 700 degrees C from 200 degrees C. The SEM images and textural analysis data signified that the pore development of carbon skeleton structure during carbonization and activation process formed and type of micropores in these pore structures was dominant.