Microwave-assisted and conventional synthesis of new phthalocyanines containing 4-(p-fluorophenyl)-3-methyl-4,5-dihydro-1H-1,2,4-triazol-5-one moieties

KAHVECI B., Oezil M., Kantar C., Sasmaz S., ISIK S., KOEYSAL Y.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol.692, no.22, pp.4835-4842, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 692 Issue: 22
  • Publication Date: 2007
  • Doi Number: 10.1016/j.jorganchem.2007.06.067
  • Journal Name: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.4835-4842
  • Keywords: microwave, synthesis, phthalocyanine, triazol-5-one, SUBSTITUTED PHTHALOCYANINES, METAL-FREE
  • Recep Tayyip Erdoğan University Affiliated: Yes

Abstract

New metal-free and metal (Zn, Ni, Cu and Co) phthalocyanines containing 4-(p-fluorophenyl)-3-methyl-4,5-dihydro-1H-1,2,4-triazol-5-one moiety have been prepared from 1-(3,4-dicyanophenyl)-4-(p-fluorophenyl)-3-methyl-4,5-dihydro-1H-1,2,4-triazol-5-one by both conventional and microwave-assisted methods. All of these compounds are soluble in CHCl3, DMF and DMSO. The new compounds have been characterized by elemental analysis, IR, NMR, UV-Vis spectroscopies. The crystal structures of compounds I and 11 were also determined by the single crystal diffraction technique. (C) 2007 Elsevier B.V. All rights reserved.