The microwave-assisted synthesis and characterization of novel, octakis(2-hydroxyethoxy)resorcinarene bridged polymeric metallophthalocyanines

KANTAR C., Agar E., ŞAŞMAZ S.

POLYHEDRON, vol.28, no.16, pp.3485-3490, 2009 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 28 Issue: 16
  • Publication Date: 2009
  • Doi Number: 10.1016/j.poly.2009.07.031
  • Journal Name: POLYHEDRON
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.3485-3490
  • Recep Tayyip Erdoğan University Affiliated: Yes

Abstract

The new metallophthalocyanine (Zn, Cu, Ni, Co) polymers containing 4,6,10,12,16,18,22,24-octakis(2-hydroxyethoxy)-2,8,14,20-tetramethylresorcinarene are described. Firstly, 4,6,10,12,16,18,22,24-octakis(2-hydroxyethoxy)-2,8,14,20-tetramethylresorcinarene compound (1) was synthesized by treating resorcinarene with 2-chloroethanol under microwave irradiation. Then, tetrakis(4,5-bis(2-hydroxyethoxy))phthalonitrile substituted resorcinarene compound (2) and octakis(4-(2-hydroxyethoxy))phthalonitrile substituted resorcinarene compound (3) were synthesized by treating compound (1) with 4,5-dichloro-1,2-dicyanobenzene and 4-nitro-1,2-dicyanobenzene, respectively, under microwave irradiation. The chlorides Cu (II), Ni (II), Co (II), were employed in order to synthesize the corresponding metallophthalocyanine polymers (2b-d and 3b-d) and Zn(CH(3)COO)(2) was used for the preparation of zinc phthalocyanine polymers (2a and 3a). All products were synthesized by microwave-assisted synthesis method. The structures were characterized by elemental analyses, (1)H NMR, (13)C NMR, UV-Vis and FTIR spectroscopy. (c) 2009 Elsevier Ltd. All rights reserved.