Microwave-assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four 14-membered tetraaza macrocycles

BIYIKLIOGLU Z., KANTEKIN H., Oezil M.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.692, sa.12, ss.2436-2440, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 692 Sayı: 12
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1016/j.jorganchem.2007.02.013
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2436-2440
  • Anahtar Kelimeler: phthalocyanine, tetraazamacrocycle, template effect, macrocyclization, tosylation, SUBSTITUTED PHTHALOCYANINES
  • Recep Tayyip Erdoğan Üniversitesi Adresli: Evet

Özet

The novel tetrasubstituted metal-free phthalocyanine (6) and metallophthalocyanines (7, 8) bearing four 14-membered tetraaza macrocycles moieties on peripheral positions have been synthesized by cyclotetramerization reaction of phthalonitrile derivative (5) in a multi-step reaction sequence. The new compounds were characterized by a combination of IR, H-1 NMR, C-13 NMR, UV-vis, elemental analysis and MS spectral data. (c) 2007 Elsevier B.V. All rights reserved.