Synthesis and properties of the phthalocyanines containing eugenol (4-allyl-2-methoxyphenol)


Agar E., Sasmaz S., Agar A.

TURKISH JOURNAL OF CHEMISTRY, vol.23, no.2, pp.131-137, 1999 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 23 Issue: 2
  • Publication Date: 1999
  • Title of Journal : TURKISH JOURNAL OF CHEMISTRY
  • Page Numbers: pp.131-137

Abstract

New metal-free and metallophthalocyanines (M=Cu(II), Ni(II), Co(II), Zn(II) and Fe(II)) substituted with eugenol (4-allyl-2-methoxyphenol) from 1,2-dicyano-4-nitrobenzen are described. Cyclotetramerization of the substituted phthalonitrile leads to a product very soluble in common organic solvents. The characterization of the compounds was accomplished by elemental analysis, H-1 NMR, C-13 NMR, IR and UV-VIS spectral data.