Microwave-assisted synthesis, characterization and spectral properties of non-peripherally tetra-substituted phthalocyanines containing eugenol moieties

KANTAR C., Sahin Z. S., Buyukgungor O., Sasmaz S.

JOURNAL OF MOLECULAR STRUCTURE, vol.1089, pp.48-52, 2015 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 1089
  • Publication Date: 2015
  • Doi Number: 10.1016/j.molstruc.2015.02.044
  • Journal Name: JOURNAL OF MOLECULAR STRUCTURE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.48-52
  • Recep Tayyip Erdoğan University Affiliated: Yes

Abstract

The microwave-assisted synthesis and characterization of novel non-peripherally eugenol substituted metallophthalocyanines (M: Co(II), Ni(II), Cu(II), Zn(II)) have been reported for the first time in this study. All the new compounds were characterized by a combination of FT-IR, H-1 NMR, C-13 NMR, and UV/vis spectroscopy techniques. The crystal structure of compound (1) was also determined by the single crystal diffraction technique. Newly synthesized eugenol substituted phthalocyanines have more redshift Q bands (about 17-18 nm) than previously reported eugenol substituted phthalocyanines. Zinc(II)phthalocyanine (1d) has an extra absorption band at 746 nm that calling "X band" at UV/vis spectrum. (C) 2015 Elsevier B.V. All rights reserved.