Water-soluble phthalocyanines containing azo dye; microwave-assisted synthesis and photochemical properties of ZnPcs

KANTAR C., ATACI E., Sasmaz S.

TURKISH JOURNAL OF CHEMISTRY, vol.38, no.6, pp.1185-1200, 2014 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 38 Issue: 6
  • Publication Date: 2014
  • Doi Number: 10.3906/kim-1404-35
  • Journal Name: TURKISH JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.1185-1200
  • Keywords: Phthalocyanine, microwave, azo dye, photochemical properties, SINGLET OXYGEN, SUBSTITUTED PHTHALOCYANINES, PHOTOPHYSICAL PROPERTIES, METALLOPHTHALOCYANINES, PORPHYRINS, COMPLEXES, SOLVENTS, SYSTEMS
  • Recep Tayyip Erdoğan University Affiliated: Yes

Abstract

Novel water-soluble metallophthalocyanines (M: Co, Ni, Cu, Zn) containing azo dye were characterized. The structures were confirmed by IR, UV/vis, H-1 NMR, C-13 NMR, mass spectroscopy, and elemental analysis. Photochemical properties and aggregation behavior of zinc phthalocyanines were investigated. Singlet oxygen quantum yields of the zinc phthalocyanines (2d, 3d, 5d, and 6d) were 0.8, 0.57, 0.71, and 0.46, respectively.