Water-soluble phthalocyanines containing azo dye; microwave-assisted synthesis and photochemical properties of ZnPcs

KANTAR C., ATACI E., Sasmaz S.

TURKISH JOURNAL OF CHEMISTRY, cilt.38, sa.6, ss.1185-1200, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 38 Sayı: 6
  • Basım Tarihi: 2014
  • Doi Numarası: 10.3906/kim-1404-35
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.1185-1200
  • Anahtar Kelimeler: Phthalocyanine, microwave, azo dye, photochemical properties, SINGLET OXYGEN, SUBSTITUTED PHTHALOCYANINES, PHOTOPHYSICAL PROPERTIES, METALLOPHTHALOCYANINES, PORPHYRINS, COMPLEXES, SOLVENTS, SYSTEMS
  • Recep Tayyip Erdoğan Üniversitesi Adresli: Evet

Özet

Novel water-soluble metallophthalocyanines (M: Co, Ni, Cu, Zn) containing azo dye were characterized. The structures were confirmed by IR, UV/vis, H-1 NMR, C-13 NMR, mass spectroscopy, and elemental analysis. Photochemical properties and aggregation behavior of zinc phthalocyanines were investigated. Singlet oxygen quantum yields of the zinc phthalocyanines (2d, 3d, 5d, and 6d) were 0.8, 0.57, 0.71, and 0.46, respectively.