Water-soluble phthalocyanines containing azo dye; microwave-assisted synthesis and photochemical properties of ZnPcs


KANTAR C. , ATACI E., Sasmaz S.

TURKISH JOURNAL OF CHEMISTRY, vol.38, no.6, pp.1185-1200, 2014 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 38 Issue: 6
  • Publication Date: 2014
  • Doi Number: 10.3906/kim-1404-35
  • Title of Journal : TURKISH JOURNAL OF CHEMISTRY
  • Page Numbers: pp.1185-1200

Abstract

Novel water-soluble metallophthalocyanines (M: Co, Ni, Cu, Zn) containing azo dye were characterized. The structures were confirmed by IR, UV/vis, H-1 NMR, C-13 NMR, mass spectroscopy, and elemental analysis. Photochemical properties and aggregation behavior of zinc phthalocyanines were investigated. Singlet oxygen quantum yields of the zinc phthalocyanines (2d, 3d, 5d, and 6d) were 0.8, 0.57, 0.71, and 0.46, respectively.