Synthesis and properties of 1,4-bis[N-(2-tolylsulphonylaminoethyl)]-1,4-diazacyclohexane bridged network polymeric phthalocyanines

AKDEMIR N., AGAR E., Sasmaz S., GUMRUKCUOGLU I., CELEBI T.

DYES AND PIGMENTS, vol.69, pp.1-6, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 69
  • Publication Date: 2006
  • Doi Number: 10.1016/j.dyepig.2005.01.013
  • Journal Name: DYES AND PIGMENTS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1-6
  • Recep Tayyip Erdoğan University Affiliated: Yes

Abstract

1,4-Bis[N-(2-tolylsulphonylaminoethyl)]-1,4-diazacyclohexane bridged metal-free and metal phthalocyanine polymers were prepared. The metal-free phthalocyanine polymer was obtained by the reaction of 4,4'-[2,2'-(piperidine-1.4-diyldiethylene)di(tosylimino)ldiphthalonitrile with hydroquinone. The chloride derivatives of Cu(I), Ni(II) and Co(II) were employed in order to synthesize the corresponding metal-phthalocyanine polymers. Zn(CH3CO2)2 was used for the preparation of the zincphthalocyanine polymer. For the preparation of the Co-containing polymer, ammonium molybdate had to be added as catalyst. The new polymers have been characterized by elemental analysis, IR, NMR, UV-VIS and DTA. (c) 2005 Elsevier Ltd. All rights reserved.