Kinetic study of vinyl polymerization with a new oligo azo peroxidic initiator


VOLGA C., HAZER B., Torul O.

EUROPEAN POLYMER JOURNAL, cilt.33, ss.907-912, 1997 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 33 Konu: 6
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1016/s0014-3057(96)00181-4
  • Dergi Adı: EUROPEAN POLYMER JOURNAL
  • Sayfa Sayıları: ss.907-912

Özet

Oligo (4,4'-azobis-cyanopentanoyl-5-peroxy-2,5-dimethyl-n-hexylperoxide), Lu-Ab, was synthesized by the interfacial condensation of 4,4'-azobis-(4-cyanopentanoyl chloride) with 2,5-dimethyl-2,5-dihydroperoxyhexane in the presence of a base. The molecular weight of the initiator was determined to be 1586 g/mol by gel permeation chromatography (GPC). Oligo-azoperoxide, Lu-Ab, was characterized by infrared and nuclear magnetic resonance spectroscopies.