Microwave-assisted synthesis and characterization of differently substituted phthalocyanines containing 3,5-dimethoxyphenol and octanethiol moieties

KANTAR C., AKDEMIR N., AGAR E., OCAK N., Sasmaz S.

DYES AND PIGMENTS, cilt.76, sa.1, ss.7-12, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 76 Sayı: 1
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.dyepig.2006.08.005
  • Dergi Adı: DYES AND PIGMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.7-12
  • Anahtar Kelimeler: phthalocyanines, complexes, X-ray diffraction, microwave-assisted, METALLOPHTHALOCYANINES, TETRAAZAMACROCYCLES
  • Recep Tayyip Erdoğan Üniversitesi Adresli: Evet

Özet

New differently substituted metal-free and metal (Cu, Zn) phthalocyanines are described. One group (1, 2, 3) contains peripheral 3,5-dimethoxyphenoxy and chloro substituents and the other group (4, 5, 6) contains 3,5-dimethoxyphenoxy and octanethiol substituents. All products were synthesized by both classical and microwave-assisted methods. Structures were confirmed by elemental analysis, H-1 NMR, C-13 NMR, UV/vis and FTIR spectroscopies. The crystal structure of starting material I was also determined using a single crystal diffraction technique. All of the complexes were only slightly soluble in polar solvents such as CHCl3, DMF and DMSO. (C) 2006 Elsevier Ltd. All rights reserved.