Role of the local structure in superconductivity of LaO0.5F0.5BiS2-xSex system

PARIS E., MIZUGUCHI Y., Hacisalihoglu M. Y., HIROI T., JOSEPH B., Aquilanti G., ...Daha Fazla

JOURNAL OF PHYSICS-CONDENSED MATTER, cilt.29, sa.14, 2017 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 29 Sayı: 14
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1088/1361-648x/aa5e97
  • Dergi Adı: JOURNAL OF PHYSICS-CONDENSED MATTER
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Anahtar Kelimeler: BiS2-based superconductors, effect of substitution, local structure and disorder, CHEMICAL PRESSURE
  • Recep Tayyip Erdoğan Üniversitesi Adresli: Evet

Özet

We have studied the local structure of LaO0.5F0.5BiS2-xSex by Bi L-1-edge extended x-ray absorption fine structure (EXAFS). We find a significant effect of Se substitution on the local atomic correlations with a gradual elongation of average in-plane Bi-S bondlength. The associated mean square relative displacement, measuring average local distortions in the BiS2 plane, hardly shows any change for small Se substitution, but decreases significantly for x >= 0.6. The Se substitution appears to suppress the local distortions within the BiS2 plane that may optimize in-plane orbital hybridization and hence the superconductivity. The results suggest that the local structure of the BiS2-layer is one of the key ingredients to control the physical properties of the BiS2-based dichalcogenides.