There are several studies about phthalocyanines containing resorcinarene groups at literature. However, their heavy metal ion extraction properties are unknown. Therefore, the novel phthalocyanines containing tetra and octa resorcinarene cavitands were synthesized and investigated extraction properties for some environmentaly important heavy metal ions. The structures were characterized by elemental analysis, H-1 NMR, C-13 NMR, UV/vis and FT-IR spectroscopy techniques. The extraction capacities were analyzed through liquid-liquid extraction method. The novel phthalocyanine compounds TP5ZnPc and TP6ZnPc seem to be proper for the removal of heavy metal cations.