PHTHALOCYANINES CONTAINING RESORCINARENE CAVITANDS; SYNTHESIS AND HEAVY METAL ION EXTRACTION PROPERTIES

Kantar C.

REVUE ROUMAINE DE CHIMIE, vol.64, no.4, pp.361-367, 2019 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 64 Issue: 4
  • Publication Date: 2019
  • Doi Number: 10.33224/rrch/2019.64.4.09
  • Journal Name: REVUE ROUMAINE DE CHIMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.361-367
  • Keywords: phthalocyanine, resorcinarene, heavy metal ion extraction, liquid-liquid extraction, cavitand, COMPLEXATION
  • Recep Tayyip Erdoğan University Affiliated: Yes

Abstract

There are several studies about phthalocyanines containing resorcin[4]arene groups at literature. However, their heavy metal ion extraction properties are unknown. Therefore, the novel phthalocyanines containing tetra and octa resorcin[4]arene cavitands were synthesized and investigated extraction properties for some environmentaly important heavy metal ions. The structures were characterized by elemental analysis, H-1 NMR, C-13 NMR, UV/vis and FT-IR spectroscopy techniques. The extraction capacities were analyzed through liquid-liquid extraction method. The novel phthalocyanine compounds TP5ZnPc and TP6ZnPc seem to be proper for the removal of heavy metal cations.