LIQUID LIQUID EQUILIBRIUM FOR THE TERNARY-SYSTEMS COMPOSED OF DIETHYL PHENYLMALONATE PLUS ACETIC-ACID PLUS WATER AND DIETHYL METHYLMALONATE PLUS ACETIC-ACID PLUS WATER AT 294-K, 298-K, AND 308-K

TORUL, OKTAY; GULTEKIN, N; NOHUT, S; DURAN, C

doi:10.1021/je00008a022

LIQUID LIQUID EQUILIBRIUM FOR THE TERNARY-SYSTEMS COMPOSED OF DIETHYL PHENYLMALONATE PLUS ACETIC-ACID PLUS WATER AND DIETHYL METHYLMALONATE PLUS ACETIC-ACID PLUS WATER AT 294-K, 298-K, AND 308-K

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TORUL O., GULTEKIN N., NOHUT S., DURAN C.

JOURNAL OF CHEMICAL AND ENGINEERING DATA, vol.37, no.4, pp.474-478, 1992 (SCI-Expanded)

Publication Type: Article / Article
Volume: 37 Issue: 4
Publication Date: 1992
Doi Number: 10.1021/je00008a022
Journal Name: JOURNAL OF CHEMICAL AND ENGINEERING DATA
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.474-478
Recep Tayyip Erdoğan University Affiliated: No

Abstract

Liquid-liquid equilibrium measurements for the systems diethyl phenylmalonate + acetic acid + water and diethyl methylmalonate + acetic acid + water were made at 294, 298, and 308 K. The mole fraction composition along the binodal curves was fit to a correlation equation, and tie-line results were fit by the Bachman, Hand, Othmer-Tobias, and selectivity methods. We conclude that diethyl phenylmalonate and diethyl methylmalonate can be used as solvents for extracting acetic acid from its aqueous solutions.